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Science of dry etching of III-V materials

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Science of dry etching of III-V materials

Auteurs : RBID : ISTEX:10854_1994_Article_BF00717875.pdf

Abstract

A review is given of dry etching of III-V semiconductors. Gas chemistries based on chlorine have traditionally been used for plasma etching of these materials due to the volatilities of both group III and group V chlorides. Recent work on the use of iodine- or bromine-based discharges has shown promising results, although the corrosiveness of the feedstock gases is of concern. For indium-containing III-V semiconductors, CH4/H2 plasmas have produced smooth anisotropic etching at relatively low rates. In applications requiring etch rates near 1 μm min−1, Cl2/CH4/H2 electron cyclotron resonance discharges have proved effective. Examples are given of the structural and chemical changes induced in the semiconductor as a result of dry etching, due to the combined effects of energetic ion bombardment and preferential removal of one of the lattice constituents. Applications for dry etching in modern microelectronic fabrication range from shallow (∼30 nm) mesa formation to creation of through-wafer via holes typically ∼100 μm deep.

DOI: 10.1007/BF00717875

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<div type="abstract" xml:lang="eng">A review is given of dry etching of III-V semiconductors. Gas chemistries based on chlorine have traditionally been used for plasma etching of these materials due to the volatilities of both group III and group V chlorides. Recent work on the use of iodine- or bromine-based discharges has shown promising results, although the corrosiveness of the feedstock gases is of concern. For indium-containing III-V semiconductors, CH4/H2 plasmas have produced smooth anisotropic etching at relatively low rates. In applications requiring etch rates near 1 μm min−1, Cl2/CH4/H2 electron cyclotron resonance discharges have proved effective. Examples are given of the structural and chemical changes induced in the semiconductor as a result of dry etching, due to the combined effects of energetic ion bombardment and preferential removal of one of the lattice constituents. Applications for dry etching in modern microelectronic fabrication range from shallow (∼30 nm) mesa formation to creation of through-wafer via holes typically ∼100 μm deep.</div>
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<abstract lang="eng">A review is given of dry etching of III-V semiconductors. Gas chemistries based on chlorine have traditionally been used for plasma etching of these materials due to the volatilities of both group III and group V chlorides. Recent work on the use of iodine- or bromine-based discharges has shown promising results, although the corrosiveness of the feedstock gases is of concern. For indium-containing III-V semiconductors, CH4/H2 plasmas have produced smooth anisotropic etching at relatively low rates. In applications requiring etch rates near 1 μm min−1, Cl2/CH4/H2 electron cyclotron resonance discharges have proved effective. Examples are given of the structural and chemical changes induced in the semiconductor as a result of dry etching, due to the combined effects of energetic ion bombardment and preferential removal of one of the lattice constituents. Applications for dry etching in modern microelectronic fabrication range from shallow (∼30 nm) mesa formation to creation of through-wafer via holes typically ∼100 μm deep.</abstract>
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